陕西煤业化工技术研究院有限责任公司;
锂离子电池作为目前商业化应用最成熟的电化学储能载体之一,在消费电子、交通工具、储能电站领域得到广泛应用。组成锂离子电池的关键材料一般是正极、负极、电解液和隔膜,其中负极材料的选择决定电池能量密度、电化学性能、安全可靠性等各方面性能,因此近20年来,负极材料技术一直是新能源产业最热门的研发领域之一。根据负极材料产业化的时间顺序,基本上可以分为三代产品,分别为碳、钛酸锂和硅基材料。文中简要介绍了三代负极材料的结构特征、功能特点、改进方向等方面研发进展,对各类负极材料存在的不足和改性等方面的研究成果进行了评述。
3,813 | 28 | 41 |
下载次数 | 被引频次 | 阅读次数 |
[1]CHENG Q,YUGE R,NAKAHARA K,et al.KOHetched graphite for fast chargeable lithium-ion batteries[J].Journal of Power Sources,2015,284:116-123.
[2]WU Y P,HOLZE R.Anode materials for lithium ion batteries obtained by mild and uniformly controlled oxidation of natural graphite[J].Journal of Solid State Electrochemistry,2003,8(1):73-78.
[3]MATSUMOTOK,LI J,OHZAWA Y,et al.surface structure and electrochemical characteristics of natural graphite fluorinated by Cl F3[J].Journal of fluorine chemistry,2006,127(10):1383-1389.
[4]刘萍,张俊英,张娜,等.软碳掺杂对大容量锂离子电池性能的影响[J].电源技术,2016,40(11):2122-2123.
[5]LIU J L,WANG J,XIA Y Y.A new rechargeable lithium ion battery with a x Li2MnO3·(1-x)Li Mn0.4Ni0.4Co0.2O2Cathode and a hard carbon anode[J].Electrochemical Acta,2011,56(21):7392-7396.
[6]LIAO X F,YU J,GAO L J.Electrochemical study on lithium iron phosphate/hard carbon lithium-ion batteries[J].J.Solid State Electrochem,2012,16(2):423-428.
[7]ZHANG Y.An affordable manufacturing method to boost the initial coulombic efficiency of disproportionate Si O lithium-ion battery anodes[J].Journal of Power Sources,2019,426:116-123.
[8]ZHAO H,WANG Z,LU P,et al.Toward practical of functional conductive polymer binder for high-energy lithium-ion battery design[J].Nano Letters,2014,14(11):6704-6710.
[9]KIM H J,CHOI S,LEE S J,et al.Controlled prelithiation of silicon monoxide for high performance lithium-ion rechargeable batteries[J].Journal of American Chemical Society,2015,137(26):8372-8375.
基本信息:
DOI:
中图分类号:TM912
引用信息:
[1]刘琪,郑德英,胡秋晨等.锂离子电池负极材料的研究进展[J].陕西煤炭,2020,39(S1):21-24+46.
基金信息:
陕西省重点研发项目(2017ZDCXL-GY-08-03)